Fulleropyrrolidine- and fulleropyrrolidinium-based donor– acceptor ensembles, C60–Fc, were tested in view of intrinsic reorganisation energies for light-induced electron transfer events; overall, the zwitterionic character of the reduced fulleropyrrolidinium acceptor plays a central role in accelerating charge separation and decelerating charge recombination
Small reorganisation energy and unique stabilisation of zwitterionic C60–acceptor moieties
DA ROS, TATIANA;BOSI, Susanna;PRATO, MAURIZIO
2002-01-01
Abstract
Fulleropyrrolidine- and fulleropyrrolidinium-based donor– acceptor ensembles, C60–Fc, were tested in view of intrinsic reorganisation energies for light-induced electron transfer events; overall, the zwitterionic character of the reduced fulleropyrrolidinium acceptor plays a central role in accelerating charge separation and decelerating charge recombinationFile in questo prodotto:
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