In the title compound, [Hg(C17H15N2S2)2], the HgII ion lies on a crystallographic twofold rotation axis giving a very distorted tetrahedral coordination geometry best described as bisphenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitrogen and the thiolate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75 (10) . In the crystal, weak C—H S interactions give rise to chains extending along the c axis.
Bis[benzyl N′-(3-phenylprop-2-enylidene)dithiocarbazato- κ2N′,S]mercury(II)
ZANGRANDO, ENNIO
2012-01-01
Abstract
In the title compound, [Hg(C17H15N2S2)2], the HgII ion lies on a crystallographic twofold rotation axis giving a very distorted tetrahedral coordination geometry best described as bisphenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitrogen and the thiolate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75 (10) . In the crystal, weak C—H S interactions give rise to chains extending along the c axis.File in questo prodotto:
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