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EnglishThe addition of nitrile oxides to [60]fullerene, leading to isoxazolinofullerenes, can be reversed using reducing agents such as Mo(CO)6 or DIBALH. Thus, this reaction can be used, in principle, for protection/deprotection of [60]fullerene or for solubilization purposes. The tether-controlled tandem addition of nitrile oxides and azomethine ylides provides mainly cis-1 patterns. The determination of the structure of bisadducts was obtained by NMR spectroscopy with the help of HMQC, HMBC, and NOEDS techniques. The isoxazoline moiety could be removed using Mo(CO)6 leaving a fulleropyrrolidine derivative
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http://hdl.handle.net/11368/1693496| Titolo: | Additions of Azomethine Ylides to Fullerene C60 Assisted by a Removable Anchor |
| Autori interni: | DA ROS, TATIANA PRATO, MAURIZIO |
| Data di pubblicazione: | 2000 |
| Rivista: | JOURNAL OF ORGANIC CHEMISTRY |
| Abstract: | The addition of nitrile oxides to [60]fullerene, leading to isoxazolinofullerenes, can be reversed using reducing agents such as Mo(CO)6 or DIBALH. Thus, this reaction can be used, in principle, for protection/deprotection of [60]fullerene or for solubilization purposes. The tether-controlled tandem addition of nitrile oxides and azomethine ylides provides mainly cis-1 patterns. The determination of the structure of bisadducts was obtained by NMR spectroscopy with the help of HMQC, HMBC, and NOEDS techniques. The isoxazoline moiety could be removed using Mo(CO)6 leaving a fulleropyrrolidine derivative |
| Handle: | http://hdl.handle.net/11368/1693496 |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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