A novel fullerene–Ru–porphyrin conjugate (3b) for Langmuir–Blodgett (LB) film deposition has been synthesized. The side polar chain that characterizes the complex is necessary to introduce enough amphiphilicity in these otherwise non-polar moieties. The complex can be deposited on solid substrates via the LB technique and the films obtained show charge separation upon light irradiation. In addition, a careful cyclic voltammetry study of the complex is reported.
Synthesis, Electrochemistry, Langmuir-Blodgett Deposition and Photophysics of Metal-Coordinated Fullerene-Porphyrin Dyads / DA ROS, Tatiana; Prato, Maurizio; M., Carano; P., Ceroni; F., Paolucci; S., Roffia; L., Valli; D. M., Guldi. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - STAMPA. - 599/1:(2000), pp. 62-68.
Synthesis, Electrochemistry, Langmuir-Blodgett Deposition and Photophysics of Metal-Coordinated Fullerene-Porphyrin Dyads
DA ROS, TATIANA;PRATO, MAURIZIO;
2000-01-01
Abstract
A novel fullerene–Ru–porphyrin conjugate (3b) for Langmuir–Blodgett (LB) film deposition has been synthesized. The side polar chain that characterizes the complex is necessary to introduce enough amphiphilicity in these otherwise non-polar moieties. The complex can be deposited on solid substrates via the LB technique and the films obtained show charge separation upon light irradiation. In addition, a careful cyclic voltammetry study of the complex is reported.Pubblicazioni consigliate
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