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EnglishThe cyclic voltammetry of a series of soluble N-methylfulleropyrrolidinium salts shows that these materials are better electron-acceptors than unmodi®ed C60. The stability of mono-reduced, zwitterionic, and doubly-reduced anionic species, produced either electrochemically or chemically, has been checked by absorption spectroscopy. Langmuir±Blodgett (LB) layers of the C60 derivatives mixed with tricosanoic acid have been built up on different substrates. The optical properties of the ®lms have been characterized using absorption spectroscopy and their structure was investigated by X-ray diffraction.
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http://hdl.handle.net/11368/1693501| Titolo: | Novel Fulleropyrrolidinium-Based Materials |
| Autori interni: | DA ROS, TATIANA PRATO, MAURIZIO |
| Data di pubblicazione: | 2000 |
| Rivista: | JOURNAL OF MATERIALS CHEMISTRY |
| Abstract: | The cyclic voltammetry of a series of soluble N-methylfulleropyrrolidinium salts shows that these materials are better electron-acceptors than unmodi®ed C60. The stability of mono-reduced, zwitterionic, and doubly-reduced anionic species, produced either electrochemically or chemically, has been checked by absorption spectroscopy. Langmuir±Blodgett (LB) layers of the C60 derivatives mixed with tricosanoic acid have been built up on different substrates. The optical properties of the ®lms have been characterized using absorption spectroscopy and their structure was investigated by X-ray diffraction. |
| Handle: | http://hdl.handle.net/11368/1693501 |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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