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EnglishThe oxygen storage capacity of Ce 0.2Zr 0.8O 2 solid solutions, prepared by different synthesis routes and aged at 1000°C, is investigated by means of temperature-programmed reduction, total- and dynamic-OSC measurements. The use of CO and H 2 as reducing agent is compared under dynamic conditions. It is observed that the dynamic OSC is critically dependent on sample pre-treatment and the nature of the reducing agent in the texturally unstable sample. In contrast, on a thermally stable Ce 0.2Zr 0.8O 2 only minor effects of the pre-treatment upon dynamic OSC are noticed.
| Titolo: | Dependency of the oxygen storage capacity in zirconia-ceria solid solutions upon textural properties | |
| Autori: | ||
| Data di pubblicazione: | 2001 | |
| Rivista: | ||
| Abstract: | The oxygen storage capacity of Ce 0.2Zr 0.8O 2 solid solutions, prepared by different synthesis routes and aged at 1000°C, is investigated by means of temperature-programmed reduction, total- and dynamic-OSC measurements. The use of CO and H 2 as reducing agent is compared under dynamic conditions. It is observed that the dynamic OSC is critically dependent on sample pre-treatment and the nature of the reducing agent in the texturally unstable sample. In contrast, on a thermally stable Ce 0.2Zr 0.8O 2 only minor effects of the pre-treatment upon dynamic OSC are noticed. | |
| Handle: | http://hdl.handle.net/11368/1694249 | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1023/A:1016682831177 | |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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