Fulleropyrrolidine- and fulleropyrrolidinium-based donor– acceptor ensembles, C60–Fc, were tested in view of intrinsic reorganisation energies for light-induced electron transfer events; overall, the zwitterionic character of the reduced fulleropyrrolidinium acceptor plays a central role in accelerating charge separation and decelerating charge recombination
Small reorganisation energy and unique stabilisation of zwitterionic C60–acceptor moieties / D. M., Guldi; C., Luo; DA ROS, Tatiana; Bosi, Susanna; Prato, Maurizio. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - (2002), pp. 2320-2321.
Small reorganisation energy and unique stabilisation of zwitterionic C60–acceptor moieties
DA ROS, TATIANA;BOSI, Susanna;PRATO, MAURIZIO
2002-01-01
Abstract
Fulleropyrrolidine- and fulleropyrrolidinium-based donor– acceptor ensembles, C60–Fc, were tested in view of intrinsic reorganisation energies for light-induced electron transfer events; overall, the zwitterionic character of the reduced fulleropyrrolidinium acceptor plays a central role in accelerating charge separation and decelerating charge recombinationFile in questo prodotto:
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