Particularly effective: The self-assembly of triazacyclonane-functionalized thiols on the surface of nanosize gold particles provides a facile entry to functional gold nanoparticles that, upon complexation with ZnII, turn into powerful catalysts for the cleavage of phosphate esters (see scheme). Because of their RNase-like behavior they are dubbed nanozymes.
Nanozymes: Gold-nanoparticles-based Transphosphorylation Catalysts / Manea, F.; BODAR HOUILLON, F.; Pasquato, Lucia; Scrimin, P.. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 43:(2004), pp. 6165-6169. [10.1002/anie.200460649]
Nanozymes: Gold-nanoparticles-based Transphosphorylation Catalysts
PASQUATO, LUCIA;
2004-01-01
Abstract
Particularly effective: The self-assembly of triazacyclonane-functionalized thiols on the surface of nanosize gold particles provides a facile entry to functional gold nanoparticles that, upon complexation with ZnII, turn into powerful catalysts for the cleavage of phosphate esters (see scheme). Because of their RNase-like behavior they are dubbed nanozymes.File in questo prodotto:
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