Baker's yeast reduction of 3-(2-nitroethyl)-tetrahydro-4H-pyran-4-one 10 and 3-(2-nitroethyl)-tetrahydro-4H-thiopyran-4-one 11 gave the corresponding optically active cis alcohols with good diastereo- and enantioselectivity. The unreacted optically active ketones were also isolated.



Titolo: Baker's Yeast reduction of 4-hetero-2-(2-nitroethyl)cyclohexanones
Autori: 
FORZATO, Cristina
NITTI, PATRIZIA
PITACCO, GIULIANA
VALENTIN, ENNIO
Data di pubblicazione: 1997
Rivista: 
TETRAHEDRON-ASYMMETRY  
Abstract: Baker's yeast reduction of 3-(2-nitroethyl)-tetrahydro-4H-pyran-4-one 10 and 3-(2-nitroethyl)-tetrahydro-4H-thiopyran-4-one 11 gave the corresponding optically active cis alcohols with good diastereo- and enantioselectivity. The unreacted optically active ketones were also isolated.
Handle: http://hdl.handle.net/11368/1699331
Digital Object Identifier (DOI): http://dx.doi.org/10.1016/S0957-4166(97)00191-2
Appare nelle tipologie:1.1 Articolo in Rivista

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