Baker's yeast reduction of 3-(2-nitroethyl)-tetrahydro-4H-pyran-4-one 10 and 3-(2-nitroethyl)-tetrahydro-4H-thiopyran-4-one 11 gave the corresponding optically active cis alcohols with good diastereo- and enantioselectivity. The unreacted optically active ketones were also isolated.
Baker's Yeast reduction of 4-hetero-2-(2-nitroethyl)cyclohexanones / Forzato, Cristina; Nitti, Patrizia; Pitacco, Giuliana; Valentin, Ennio. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 8:(1997), pp. 1811-1820. [10.1016/S0957-4166(97)00191-2]
Baker's Yeast reduction of 4-hetero-2-(2-nitroethyl)cyclohexanones
FORZATO, Cristina;NITTI, PATRIZIA;PITACCO, GIULIANA;VALENTIN, ENNIO
1997-01-01
Abstract
Baker's yeast reduction of 3-(2-nitroethyl)-tetrahydro-4H-pyran-4-one 10 and 3-(2-nitroethyl)-tetrahydro-4H-thiopyran-4-one 11 gave the corresponding optically active cis alcohols with good diastereo- and enantioselectivity. The unreacted optically active ketones were also isolated.File in questo prodotto:
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