Poly(ethylene glycol)-Supported Copper(II) Triazacyclononane: an Efficient, Recoverable, and Recyclable Catalyst for the Cleavage of a Phosphodiester

1,3,5-Triazacyclononane macrocycle has been linked to the soluble polymer monomethoxy poly(ethyleneglycol) and its copper(II) complex efficiently catalyzes the hydrolysis of a model phosphodiester. The catalyst, easily recovered from the water solution, shows no appreciable loss of activity when recycled up to three times.



Titolo: Poly(ethylene glycol)-Supported Copper(II) Triazacyclononane: an Efficient, Recoverable, and Recyclable Catalyst for the Cleavage of a Phosphodiester
Autori: 
DRIOLI, Sara
FELLUGA, FULVIA
TECILLA, PAOLO
mostra contributor esterni 
Data di pubblicazione: 2003
Rivista: 
TETRAHEDRON LETTERS  
Abstract: 1,3,5-Triazacyclononane macrocycle has been linked to the soluble polymer monomethoxy poly(ethyleneglycol) and its copper(II) complex efficiently catalyzes the hydrolysis of a model phosphodiester. The catalyst, easily recovered from the water solution, shows no appreciable loss of activity when recycled up to three times.
Handle: http://hdl.handle.net/11368/1701671
Digital Object Identifier (DOI): http://dx.doi.org/10.1016/s0040-4039(02)02584-4
Appare nelle tipologie:1.1 Articolo in Rivista

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