1,3,5-Triazacyclononane macrocycle has been linked to the soluble polymer monomethoxy poly(ethyleneglycol) and its copper(II) complex efficiently catalyzes the hydrolysis of a model phosphodiester. The catalyst, easily recovered from the water solution, shows no appreciable loss of activity when recycled up to three times.
Poly(ethylene glycol)-Supported Copper(II) Triazacyclononane: an Efficient, Recoverable, and Recyclable Catalyst for the Cleavage of a Phosphodiester / Bonora, G. M.; Drioli, Sara; Felluga, Fulvia; Mancin, F.; Rossi, P.; Scrimin, P.; Tecilla, Paolo. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 44:(2003), pp. 535-538. [10.1016/s0040-4039(02)02584-4]
Poly(ethylene glycol)-Supported Copper(II) Triazacyclononane: an Efficient, Recoverable, and Recyclable Catalyst for the Cleavage of a Phosphodiester
DRIOLI, Sara;FELLUGA, FULVIA;TECILLA, PAOLO
2003-01-01
Abstract
1,3,5-Triazacyclononane macrocycle has been linked to the soluble polymer monomethoxy poly(ethyleneglycol) and its copper(II) complex efficiently catalyzes the hydrolysis of a model phosphodiester. The catalyst, easily recovered from the water solution, shows no appreciable loss of activity when recycled up to three times.Pubblicazioni consigliate
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