A molecule-based nanoporous material showing tuneable spin-crossover behaviour near room temperature

A FeII-based 1D open framework that exhibits room-temperature spin- crossover (SCO) is reported. This material shows a reversible structural, magnetic, and chromatic response to a sorption/desorption process, allowing the tuning of the spin-transition properties by choosing the appropriate solvent (see figure). This feature represents the first example of a bifunctional material in which host–guest properties directly influence the SCO properties.



Titolo: A molecule-based nanoporous material showing tuneable spin-crossover behaviour near room temperature
Autori: 
GEREMIA, SILVANO
mostra contributor esterni 
Data di pubblicazione: 2007
Rivista: 
ADVANCED MATERIALS  
Abstract: A FeII-based 1D open framework that exhibits room-temperature spin- crossover (SCO) is reported. This material shows a reversible structural, magnetic, and chromatic response to a sorption/desorption process, allowing the tuning of the spin-transition properties by choosing the appropriate solvent (see figure). This feature represents the first example of a bifunctional material in which host–guest properties directly influence the SCO properties.
Handle: http://hdl.handle.net/11368/1707908
Digital Object Identifier (DOI): http://dx.doi.org/10.1002/Adma.200602284
Appare nelle tipologie:1.1 Articolo in Rivista

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