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EnglishA FeII-based 1D open framework that exhibits room-temperature spin- crossover (SCO) is reported. This material shows a reversible structural, magnetic, and chromatic response to a sorption/desorption process, allowing the tuning of the spin-transition properties by choosing the appropriate solvent (see figure). This feature represents the first example of a bifunctional material in which host–guest properties directly influence the SCO properties.
| Titolo: | A molecule-based nanoporous material showing tuneable spin-crossover behaviour near room temperature | |
| Autori: | ||
| Data di pubblicazione: | 2007 | |
| Rivista: | ||
| Abstract: | A FeII-based 1D open framework that exhibits room-temperature spin- crossover (SCO) is reported. This material shows a reversible structural, magnetic, and chromatic response to a sorption/desorption process, allowing the tuning of the spin-transition properties by choosing the appropriate solvent (see figure). This feature represents the first example of a bifunctional material in which host–guest properties directly influence the SCO properties. | |
| Handle: | http://hdl.handle.net/11368/1707908 | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/Adma.200602284 | |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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