A series of γ-lactones possessing the m-menthane skeleton has been prepared from optically active cyclohexanols obtained by reduction with baker's yeast of γ-keto esters, the latter compounds deriving from 4-methylcyclohexanone via enamine formation and Stork alkylation. CD spectra are also reported.
Synthesis and CD study of optically active bicyclic gamma-lactones belonging to the m-menthane series
FORZATO, Cristina;NITTI, PATRIZIA;PITACCO, GIULIANA;VALENTIN, ENNIO
1996-01-01
Abstract
A series of γ-lactones possessing the m-menthane skeleton has been prepared from optically active cyclohexanols obtained by reduction with baker's yeast of γ-keto esters, the latter compounds deriving from 4-methylcyclohexanone via enamine formation and Stork alkylation. CD spectra are also reported.File in questo prodotto:
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