Supramolecular plasticity: The remarkable host–guest properties of phosphonate cavitands have been exploited in the self-assembly of supramolecular polymers that feature guest-triggered reversibility and template-driven conversion from linear into star-branched forms. The structurally similar but complexation-inefficient thiophosphonate cavitand acts as chain stopper to control the degree of polymerization.

Host-guest driven self-assembly of linear and star supramolecular polymers

DEMITRI, NICOLA;GEREMIA, SILVANO;
2008

Abstract

Supramolecular plasticity: The remarkable host–guest properties of phosphonate cavitands have been exploited in the self-assembly of supramolecular polymers that feature guest-triggered reversibility and template-driven conversion from linear into star-branched forms. The structurally similar but complexation-inefficient thiophosphonate cavitand acts as chain stopper to control the degree of polymerization.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11368/1856855
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