Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, γ-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h−1
Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [gamma-SiW10O36]8-: a totally inorganic oxygen-evolving catalyst / Sartorel, A; Carraro, M; Scorrano, G; DE ZORZI, Rita; Geremia, Silvano; Mcdaniel, N. D.; Bernhard, S; Bonchio, M.. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - STAMPA. - 130:(2008), pp. 5006-5007. [10.1021/ja077837f]
Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [gamma-SiW10O36]8-: a totally inorganic oxygen-evolving catalyst
DE ZORZI, RITA;GEREMIA, SILVANO;
2008-01-01
Abstract
Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, γ-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h−1File in questo prodotto:
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