Dehydrogenation of glycerol to dihydroxyacetone is catalyzed by Ir(diene)(N-N)X (diene = 1,5-hexadiene, 1,5-cyclooctadiene; N-N = 1,10-phenanthroline, 2,2′-bipyridine and substituted derivatives; X = Cl, I). The reactions are performed under hydrogen transfer conditions, using acetophenone as the hydrogen acceptor.
A novel glycerol valorization route: chemoselective dehydrogenation catalyzed by iridium derivatives
FARNETTI, ERICA;KASPAR, JAN;
2009-01-01
Abstract
Dehydrogenation of glycerol to dihydroxyacetone is catalyzed by Ir(diene)(N-N)X (diene = 1,5-hexadiene, 1,5-cyclooctadiene; N-N = 1,10-phenanthroline, 2,2′-bipyridine and substituted derivatives; X = Cl, I). The reactions are performed under hydrogen transfer conditions, using acetophenone as the hydrogen acceptor.File in questo prodotto:
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