A highly nanoporous material has been obtained by self-assembly of calixarene and porphyrin building blocks. This supramolecular zeolite-like structure was successively functionalized by diffusion and coordination of metal ions to form a new bifunctionalized nanoporous material containing a porphyrinic pigment together with a metal center.
Nanoporous crystals of calixarene/porphyrin supramolecular complex functionalized by diffusion and coordination of metal ions / DE ZORZI, Rita; Guidolin, Nicol; Randaccio, Lucio; R., Purrello; Geremia, Silvano. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - STAMPA. - 131:(2009), pp. 2487-2489. [10.1021/ja808850d]
Nanoporous crystals of calixarene/porphyrin supramolecular complex functionalized by diffusion and coordination of metal ions
DE ZORZI, RITA;GUIDOLIN, Nicol;RANDACCIO, LUCIO;GEREMIA, SILVANO
2009-01-01
Abstract
A highly nanoporous material has been obtained by self-assembly of calixarene and porphyrin building blocks. This supramolecular zeolite-like structure was successively functionalized by diffusion and coordination of metal ions to form a new bifunctionalized nanoporous material containing a porphyrinic pigment together with a metal center.Pubblicazioni consigliate
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