According to NMR evidence the metal-mediated sandwich assemblies of porphyrins 2 and 3 undergo in solution a thermally driven motion that resembles that of a stepper: the spontaneous rotational motion of the pyridyl rings is converted into a reciprocating linear motion of the porphyrins.
Concerted motions in supramolecular systems: metal-mediated assemblies of porphyrins that behave like nanometric step-machines / Iengo, Elisabetta; T., Gatti; Zangrando, Ennio; M. T., Indelli; F., Scandola; Alessio, Enzo. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 47:(2011), pp. 1616-1618. [10.1039/c0cc03513k]
Concerted motions in supramolecular systems: metal-mediated assemblies of porphyrins that behave like nanometric step-machines
IENGO, ELISABETTA;ZANGRANDO, ENNIO;ALESSIO, ENZO
2011-01-01
Abstract
According to NMR evidence the metal-mediated sandwich assemblies of porphyrins 2 and 3 undergo in solution a thermally driven motion that resembles that of a stepper: the spontaneous rotational motion of the pyridyl rings is converted into a reciprocating linear motion of the porphyrins.File in questo prodotto:
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