Three new molecular cages—a trigonal prism (2) and two cubicshaped boxes of increasing size (3, 4)—featuring as many as 10 porphyrins were obtained in quantitative yields by self-assembly of a single bis-zincporphyrin metallacycle (1) with appropriate polytopic N-linkers: the trigonal planar tpt or the cruciform porphyrins 40-TPyP and 40-TPhPyP.
Modular self-assembled multiporphyrin cages with tunable shape
ALESSIO, ENZO;CASANOVA, MASSIMO;ZANGRANDO, ENNIO;IENGO, ELISABETTA
2012-01-01
Abstract
Three new molecular cages—a trigonal prism (2) and two cubicshaped boxes of increasing size (3, 4)—featuring as many as 10 porphyrins were obtained in quantitative yields by self-assembly of a single bis-zincporphyrin metallacycle (1) with appropriate polytopic N-linkers: the trigonal planar tpt or the cruciform porphyrins 40-TPyP and 40-TPhPyP.File in questo prodotto:
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