Ca adsorption on Cu(100) has been studied by high-resolution electron energy-loss spectroscopy, work-function measurements, and low-energy electron diffraction as a function of coverage, up to one monolayer, at 110 and 300 K. At each coverage a condensed phase is formed at 110 K that irreversibly transforms into a dispersed phase upon heating. The 300-K data suggest that Ca occupies substitutional sites at this temperature. A comparison with the chemisorption of alkali metals is presented.
Ca chemisorption on Cu(100) in the submonolayer regime: Metastable and stable adsorption phases / P., Rudolf; C., Astaldi; A., Bianco; Modesti, Silvio. - In: PHYSICAL REVIEW. B, CONDENSED MATTER. - ISSN 0163-1829. - STAMPA. - 47:(1993), pp. 4123-4126. [10.1103/PhysRevB.47.4123]
Ca chemisorption on Cu(100) in the submonolayer regime: Metastable and stable adsorption phases
MODESTI, SILVIO
1993-01-01
Abstract
Ca adsorption on Cu(100) has been studied by high-resolution electron energy-loss spectroscopy, work-function measurements, and low-energy electron diffraction as a function of coverage, up to one monolayer, at 110 and 300 K. At each coverage a condensed phase is formed at 110 K that irreversibly transforms into a dispersed phase upon heating. The 300-K data suggest that Ca occupies substitutional sites at this temperature. A comparison with the chemisorption of alkali metals is presented.Pubblicazioni consigliate
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