A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.
Synthesis of a sterically modulated pyridine-NHC palladium complex and its reactivity towards ethylene / Khlebnikov, V., Meduri, A., Mueller Bunz, H., Milani, B., Albrecht, M.. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - STAMPA. - 36:(2012), pp. 1552-1555. [10.1039/c2nj40287d]
Synthesis of a sterically modulated pyridine-NHC palladium complex and its reactivity towards ethylene
MEDURI, ANGELO;MILANI, Barbara;
2012-01-01
Abstract
A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.File in questo prodotto:
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