A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.

Synthesis of a sterically modulated pyridine-NHC palladium complex and its reactivity towards ethylene

MEDURI, ANGELO;MILANI, Barbara;
2012-01-01

Abstract

A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11368/2573420
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