It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed “magic” cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B[BOND]OH groups of the hydroxy pentaaryl borazine.
"Magic" Surface Clustering of Borazines Driven by Repulsive Intermolecular Forces
BONIFAZI, DAVIDE
2013-01-01
Abstract
It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed “magic” cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B[BOND]OH groups of the hydroxy pentaaryl borazine.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
