For the fi rst time the two linkage isomers of a Ru( II ) complex with 2-(2 ’ -pyridyl)pyrimidine-4-carboxylic acid (cppH) – that form in comparable amounts – have been fully characterized individually. The X-ray structure of each isomer is related to its NMR spectrum in solution.
An irresolute linker: separation, and structural and spectroscopic characterization of the two linkage isomers of a Ru(ii)-(2-(2′-pyridyl)pyrimidine-4-carboxylic acid) complex
IENGO, ELISABETTA;BALDUCCI, GABRIELE;ALESSIO, ENZO
2014-01-01
Abstract
For the fi rst time the two linkage isomers of a Ru( II ) complex with 2-(2 ’ -pyridyl)pyrimidine-4-carboxylic acid (cppH) – that form in comparable amounts – have been fully characterized individually. The X-ray structure of each isomer is related to its NMR spectrum in solution.File in questo prodotto:
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