For the fi rst time the two linkage isomers of a Ru( II ) complex with 2-(2 ’ -pyridyl)pyrimidine-4-carboxylic acid (cppH) – that form in comparable amounts – have been fully characterized individually. The X-ray structure of each isomer is related to its NMR spectrum in solution.
Titolo: | An irresolute linker: separation, and structural and spectroscopic characterization of the two linkage isomers of a Ru(ii)-(2-(2′-pyridyl)pyrimidine-4-carboxylic acid) complex |
Autori: | |
Data di pubblicazione: | 2014 |
Rivista: | |
Abstract: | For the fi rst time the two linkage isomers of a Ru( II ) complex with 2-(2 ’ -pyridyl)pyrimidine-4-carboxylic acid (cppH) – that form in comparable amounts – have been fully characterized individually. The X-ray structure of each isomer is related to its NMR spectrum in solution. |
Handle: | http://hdl.handle.net/11368/2798729 |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/c4dt01282h |
URL: | http://pubs.rsc.org/en/journals/journalissues/dt#!issueid=dt044048&type=current&issnprint=1477-9226 |
Appare nelle tipologie: | 1.1 Articolo in Rivista |
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