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EnglishThe catalytic conversion of carbon dioxide to synthetic fuels and other valuable chemicals is an issue of global environmental and economic impact. In this report we show by means of X-ray photoelectron spectroscopy in the millibar range that, on a Ni surface, the reduction of carbon dioxide is indirectly governed by the CO chemistry. While the growth of graphene and the carbide-graphene conversion can be controlled by selecting the reaction temperature, oxygen is mainly removed by CO, since oxygen reduction by hydrogen is a slow process on Ni. Even though there is still a consistent pressure gap with respect to industrial reaction conditions, the observed phenomena provide a plausible interpretation of the behavior of Ni/Cu based catalysts for CO2 conversion and account for a possible role of CO in the methanol synthesis process.
| Titolo: | Reactivity of Carbon Dioxide on Nickel: Role of CO in the Competing Interplay between Oxygen and Graphene |
| Autori: | |
| Data di pubblicazione: | 2014 |
| Rivista: | |
| Abstract: | The catalytic conversion of carbon dioxide to synthetic fuels and other valuable chemicals is an issue of global environmental and economic impact. In this report we show by means of X-ray photoelectron spectroscopy in the millibar range that, on a Ni surface, the reduction of carbon dioxide is indirectly governed by the CO chemistry. While the growth of graphene and the carbide-graphene conversion can be controlled by selecting the reaction temperature, oxygen is mainly removed by CO, since oxygen reduction by hydrogen is a slow process on Ni. Even though there is still a consistent pressure gap with respect to industrial reaction conditions, the observed phenomena provide a plausible interpretation of the behavior of Ni/Cu based catalysts for CO2 conversion and account for a possible role of CO in the methanol synthesis process. |
| Handle: | http://hdl.handle.net/11368/2821526 |
| Digital Object Identifier (DOI): | 10.1021/jz5007675 |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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