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EnglishTwo new Ag(I) coordination polymers [Ag2(mepyz)](2,6-ndc)]n (1) and [Ag4(4,40-bipy)]4(2,6-ndc)2.8(H2O) (2) (where 2,6-ndcH2 = 2,6-napthalene dicarboxylic acid, mepyz = 2-methyl pyrazine and 4,40-bipy = 4,4'-bipyridine) have been synthesized and characterized by single crystal X-ray diffraction analysis. Complex 1 displays a 2D rectangular grid architecture comprising short Ag-Ag interactions, while 2 is a 1D coordination polymer: both enlarge their dimensionality to 3D via weak interactions. Luminescence study performed on complexes as well on ligands shows metal perturbed intraligand CT transition.
| Titolo: | 2D and 1D Coordination Polymers of Ag(I) Ions with 2,6-Naphthalenedicarboxylate and N–Donor Coligands |
| Autori: | |
| Data di pubblicazione: | 2012 |
| Rivista: | |
| Abstract: | Two new Ag(I) coordination polymers [Ag2(mepyz)](2,6-ndc)]n (1) and [Ag4(4,40-bipy)]4(2,6-ndc)2.8(H2O) (2) (where 2,6-ndcH2 = 2,6-napthalene dicarboxylic acid, mepyz = 2-methyl pyrazine and 4,40-bipy = 4,4'-bipyridine) have been synthesized and characterized by single crystal X-ray diffraction analysis. Complex 1 displays a 2D rectangular grid architecture comprising short Ag-Ag interactions, while 2 is a 1D coordination polymer: both enlarge their dimensionality to 3D via weak interactions. Luminescence study performed on complexes as well on ligands shows metal perturbed intraligand CT transition. |
| Handle: | http://hdl.handle.net/11368/2829736 |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1007/s10904-012-9780-y |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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