2D and 1D Coordination Polymers of Ag(I) Ions with 2,6-Naphthalenedicarboxylate and N–Donor Coligands

Bera, Madhusudan; Jana, Swapan Kumar; Hazari, Debdoot; Rana, Abhinandan; Chowdhuri, Durga Sankar; Puschmann, Horst; Zangrando, Ennio; Dalai, Sudipta

doi:10.1007/s10904-012-9780-y

Two new Ag(I) coordination polymers [Ag2(mepyz)](2,6-ndc)]n (1) and [Ag4(4,40-bipy)]4(2,6-ndc)2.8(H2O) (2) (where 2,6-ndcH2 = 2,6-napthalene dicarboxylic acid, mepyz = 2-methyl pyrazine and 4,40-bipy = 4,4'-bipyridine) have been synthesized and characterized by single crystal X-ray diffraction analysis. Complex 1 displays a 2D rectangular grid architecture comprising short Ag-Ag interactions, while 2 is a 1D coordination polymer: both enlarge their dimensionality to 3D via weak interactions. Luminescence study performed on complexes as well on ligands shows metal perturbed intraligand CT transition.

Titolo:	2D and 1D Coordination Polymers of Ag(I) Ions with 2,6-Naphthalenedicarboxylate and N–Donor Coligands
Autori:	Bera, Madhusudan Jana, Swapan Kumar Hazari, Debdoot Rana, Abhinandan Chowdhuri, Durga Sankar Puschmann, Horst ZANGRANDO, ENNIO Dalai, Sudipta mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	2012
Rivista:	JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Abstract:	Two new Ag(I) coordination polymers [Ag2(mepyz)](2,6-ndc)]n (1) and [Ag4(4,40-bipy)]4(2,6-ndc)2.8(H2O) (2) (where 2,6-ndcH2 = 2,6-napthalene dicarboxylic acid, mepyz = 2-methyl pyrazine and 4,40-bipy = 4,4'-bipyridine) have been synthesized and characterized by single crystal X-ray diffraction analysis. Complex 1 displays a 2D rectangular grid architecture comprising short Ag-Ag interactions, while 2 is a 1D coordination polymer: both enlarge their dimensionality to 3D via weak interactions. Luminescence study performed on complexes as well on ligands shows metal perturbed intraligand CT transition.
Handle:	http://hdl.handle.net/11368/2829736
Digital Object Identifier (DOI):	http://dx.doi.org/10.1007/s10904-012-9780-y
Appare nelle tipologie:	1.1 Articolo in Rivista

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