Two new Ag(I) coordination polymers [Ag2(mepyz)](2,6-ndc)]n (1) and [Ag4(4,40-bipy)]4(2,6-ndc)2.8(H2O) (2) (where 2,6-ndcH2 = 2,6-napthalene dicarboxylic acid, mepyz = 2-methyl pyrazine and 4,40-bipy = 4,4'-bipyridine) have been synthesized and characterized by single crystal X-ray diffraction analysis. Complex 1 displays a 2D rectangular grid architecture comprising short Ag-Ag interactions, while 2 is a 1D coordination polymer: both enlarge their dimensionality to 3D via weak interactions. Luminescence study performed on complexes as well on ligands shows metal perturbed intraligand CT transition.

2D and 1D Coordination Polymers of Ag(I) Ions with 2,6-Naphthalenedicarboxylate and N–Donor Coligands

ZANGRANDO, ENNIO;
2012

Abstract

Two new Ag(I) coordination polymers [Ag2(mepyz)](2,6-ndc)]n (1) and [Ag4(4,40-bipy)]4(2,6-ndc)2.8(H2O) (2) (where 2,6-ndcH2 = 2,6-napthalene dicarboxylic acid, mepyz = 2-methyl pyrazine and 4,40-bipy = 4,4'-bipyridine) have been synthesized and characterized by single crystal X-ray diffraction analysis. Complex 1 displays a 2D rectangular grid architecture comprising short Ag-Ag interactions, while 2 is a 1D coordination polymer: both enlarge their dimensionality to 3D via weak interactions. Luminescence study performed on complexes as well on ligands shows metal perturbed intraligand CT transition.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11368/2829736
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 8
  • ???jsp.display-item.citation.isi??? 8
social impact