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EnglishTwo new cadmium coordination polymers have been synthesized with composition {[Cd2(tma)(atz) (H2O)].(H2O)}n (1) (tmaH3 = benzene-1,3,5-tricarboxylicacid, atzH = 5-aminotetrazole) and [Cd(isoor)2(H2O)2] (2) (isoorH = isoorotic acid). X-ray single crystal structure analysis reveals that complex 1 is 3D coordination polymer. However 2 is mononuclear and turned 3D via hydrogen bonding. Thermogravimetric and luminescence characterization of the complexes were done.
| Titolo: | Synthesis, Crystal Structure, Thermal and Luminescent Characterization of Two New 3D Cadmium–Carboxylate Frameworks |
| Autori: | |
| Data di pubblicazione: | 2012 |
| Rivista: | |
| Abstract: | Two new cadmium coordination polymers have been synthesized with composition {[Cd2(tma)(atz) (H2O)].(H2O)}n (1) (tmaH3 = benzene-1,3,5-tricarboxylicacid, atzH = 5-aminotetrazole) and [Cd(isoor)2(H2O)2] (2) (isoorH = isoorotic acid). X-ray single crystal structure analysis reveals that complex 1 is 3D coordination polymer. However 2 is mononuclear and turned 3D via hydrogen bonding. Thermogravimetric and luminescence characterization of the complexes were done. |
| Handle: | http://hdl.handle.net/11368/2829745 |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1007/s10904-012-9676-x |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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