Two new cadmium coordination polymers have been synthesized with composition {[Cd2(tma)(atz) (H2O)].(H2O)}n (1) (tmaH3 = benzene-1,3,5-tricarboxylicacid, atzH = 5-aminotetrazole) and [Cd(isoor)2(H2O)2] (2) (isoorH = isoorotic acid). X-ray single crystal structure analysis reveals that complex 1 is 3D coordination polymer. However 2 is mononuclear and turned 3D via hydrogen bonding. Thermogravimetric and luminescence characterization of the complexes were done.
Synthesis, Crystal Structure, Thermal and Luminescent Characterization of Two New 3D Cadmium–Carboxylate Frameworks / Chowdhuri, Durga Sankar; Bera, Madhusudan; Rana, Abhinandan; Hazari, Debdoot; Jana, Swapan Kumar; Zangrando, Ennio; Dalai, Sudipta. - In: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS. - ISSN 1574-1443. - STAMPA. - 22:5(2012), pp. 963-972. [10.1007/s10904-012-9676-x]
Synthesis, Crystal Structure, Thermal and Luminescent Characterization of Two New 3D Cadmium–Carboxylate Frameworks
ZANGRANDO, ENNIO;
2012-01-01
Abstract
Two new cadmium coordination polymers have been synthesized with composition {[Cd2(tma)(atz) (H2O)].(H2O)}n (1) (tmaH3 = benzene-1,3,5-tricarboxylicacid, atzH = 5-aminotetrazole) and [Cd(isoor)2(H2O)2] (2) (isoorH = isoorotic acid). X-ray single crystal structure analysis reveals that complex 1 is 3D coordination polymer. However 2 is mononuclear and turned 3D via hydrogen bonding. Thermogravimetric and luminescence characterization of the complexes were done.Pubblicazioni consigliate
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