Two new cadmium coordination polymers have been synthesized with composition {[Cd2(tma)(atz) (H2O)].(H2O)}n (1) (tmaH3 = benzene-1,3,5-tricarboxylicacid, atzH = 5-aminotetrazole) and [Cd(isoor)2(H2O)2] (2) (isoorH = isoorotic acid). X-ray single crystal structure analysis reveals that complex 1 is 3D coordination polymer. However 2 is mononuclear and turned 3D via hydrogen bonding. Thermogravimetric and luminescence characterization of the complexes were done.
Synthesis, Crystal Structure, Thermal and Luminescent Characterization of Two New 3D Cadmium–Carboxylate Frameworks
ZANGRANDO, ENNIO;
2012-01-01
Abstract
Two new cadmium coordination polymers have been synthesized with composition {[Cd2(tma)(atz) (H2O)].(H2O)}n (1) (tmaH3 = benzene-1,3,5-tricarboxylicacid, atzH = 5-aminotetrazole) and [Cd(isoor)2(H2O)2] (2) (isoorH = isoorotic acid). X-ray single crystal structure analysis reveals that complex 1 is 3D coordination polymer. However 2 is mononuclear and turned 3D via hydrogen bonding. Thermogravimetric and luminescence characterization of the complexes were done.File in questo prodotto:
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