In the title complex, [Cd(C17H15N2S2)2], the CdII ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bisphenoidal. The two deprotonated Schiff base ligands chelate the CdII ion through the azomethine N and the thiolate S atom. The dihedral angle between the two chelating ligands is 84.01 (9) . Weak intermolecular C—H S interactions lead to the formation of chains along the c axis.
Bis[benzyl 3-(3-phenylprop-2-enylidene)dithiocarbazato- κ2N3,S]cadmium / Reza, M. S.; Islam, M. A. A. A. A.; Tarafder, M. T. H; Sheikh, M. C.; Zangrando, Ennio. - In: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. - ISSN 1600-5368. - 68:7(2012), pp. m976-m977. [10.1107/S1600536812028127]
Bis[benzyl 3-(3-phenylprop-2-enylidene)dithiocarbazato- κ2N3,S]cadmium
ZANGRANDO, ENNIO
2012-01-01
Abstract
In the title complex, [Cd(C17H15N2S2)2], the CdII ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bisphenoidal. The two deprotonated Schiff base ligands chelate the CdII ion through the azomethine N and the thiolate S atom. The dihedral angle between the two chelating ligands is 84.01 (9) . Weak intermolecular C—H S interactions lead to the formation of chains along the c axis.Pubblicazioni consigliate
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