The synthesis, structural elucidation and TD-DFT analysis of the self-assembly of a cobalt(II) complex with cyanuric acid is reported. The asymmetric unit in the crystal comprises a cobalt complex cation, [Co(H2CA)(H2O)5]+ (H3CA = cyanuric acid), a cyanurate mono anion, and two lattice water molecules, which are assembled in the supramolecular network via pair-wise coupling of N-H···O type occurring between the ion pairs and additional hydrogen bonds involving aqua ligands and lattice water molecules.
The supramolecular assembly of cyanurate cobalt(II) complexes: Crystal structure, TD-DFT approach and thermal study / Mistri, S.; García Granda, S.; Zangrando, Ennio; Manna, S. C.. - In: INDIAN JOURNAL OF CHEMISTRY. SECTION A, INORGANIC, BIO-INORGANIC, PHYSICAL, THEORETICAL & ANALYTICAL CHEMISTRY.. - ISSN 0376-4710. - STAMPA. - (2014), pp. 135-142.
The supramolecular assembly of cyanurate cobalt(II) complexes: Crystal structure, TD-DFT approach and thermal study
ZANGRANDO, ENNIO;
2014-01-01
Abstract
The synthesis, structural elucidation and TD-DFT analysis of the self-assembly of a cobalt(II) complex with cyanuric acid is reported. The asymmetric unit in the crystal comprises a cobalt complex cation, [Co(H2CA)(H2O)5]+ (H3CA = cyanuric acid), a cyanurate mono anion, and two lattice water molecules, which are assembled in the supramolecular network via pair-wise coupling of N-H···O type occurring between the ion pairs and additional hydrogen bonds involving aqua ligands and lattice water molecules.Pubblicazioni consigliate
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