Nucleophilic Additions to a,ß-Unsaturated Sulphones. Part III. Regiochemistry of the Reaction of (E)-Phenyl ß-Cyanovinyl Sulphone with Nitrogen, Oxygen and Carbon Nucleophiles

The reactions of the title compound with secondary amines, alcohols, and enamines have been studied. Addition or addition-elimination at either electrophilic position is observed. Regiochemistry is a function of steric and electronic effects and of electrostatic interactions



Titolo: Nucleophilic Additions to a,ß-Unsaturated Sulphones. Part III. Regiochemistry of the Reaction of (E)-Phenyl ß-Cyanovinyl Sulphone with Nitrogen, Oxygen and Carbon Nucleophiles
Autori: 
BENEDETTI, FABIO
FABRISSIN, SILVIO
PRICL, SABRINA
RISALITI, AMERIGO
Data di pubblicazione: 1987
Rivista: 
GAZZETTA CHIMICA ITALIANA  
Abstract: The reactions of the title compound with secondary amines, alcohols, and enamines have been studied. Addition or addition-elimination at either electrophilic position is observed. Regiochemistry is a function of steric and electronic effects and of electrostatic interactions
Handle: http://hdl.handle.net/11368/2853654
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