2,5-Diamide-substituted five-membered heterocycles: Challenging molecular synthons

In the present work we describe the synthetic routes for preparing unprecedented 2,5-diamido 5-membered heterocycles based on the thiophene, pyrrole and furan rings exploiting Curtius-like rearrangement reactions. Conformational analysis performed for the 2,5-diamidothiophene derivatives displayed a “closed” conformation, in which the two carbonyl O atoms are in close contact with the thiophen S atom.

Titolo: 2,5-Diamide-substituted five-membered heterocycles: Challenging molecular synthons
Autori: 
FABBRO, CHIARA
ARMANI, SIMONE
BONIFAZI, DAVIDE
mostra contributor esterni 
Data di pubblicazione: 2014
Rivista: 
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY  
Abstract: In the present work we describe the synthetic routes for preparing unprecedented 2,5-diamido 5-membered heterocycles based on the thiophene, pyrrole and furan rings exploiting Curtius-like rearrangement reactions. Conformational analysis performed for the 2,5-diamidothiophene derivatives displayed a “closed” conformation, in which the two carbonyl O atoms are in close contact with the thiophen S atom.
Handle: http://hdl.handle.net/11368/2855741
Digital Object Identifier (DOI): http://dx.doi.org/10.1002/ejoc.201402654
Appare nelle tipologie:1.1 Articolo in Rivista

File in questo prodotto:
Non ci sono file associati a questo prodotto.
Utilizza questo identificativo per citare o creare un link a questo documento:
http://hdl.handle.net/11368/2855741
  • Citazioni
  • PubMed Central ND
  • Scopus
  • WOS
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
 
 
 
©2014 University of Trieste dove siamo Privacy
Piazzale Europa,1 34127 Trieste, Italia - Tel. +39 040.558.7111 - P.IVA 00211830328 - C.F. 80013890324 - P.E.C.: ateneo@pec.units.it
 Copyright © 2022