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EnglishWe report the formation of a metal-organic network on a BN/Cu(111) template by codeposition of carbonitrile-functionalized porphyrin derivatives (2H-TPCN) with Co atoms in an ultrahigh vacuum environment. The resulting metallo-supramolecular structure explored by scanning tunneling microscopy and spectroscopy features a distinct 4-fold coordination motif. Furthermore, we demonstrate an in situ metalation of the tetrapyrrole macrocycles with deposited Co atoms yielding Co-TPCN directly on the BN sheet. Our results provide perspectives for the formation of coordination networks on BN and related systems featuring structural, electronic, and magnetic properties unachievable on metallic supports.
| Titolo: | Controlling coordination reactions and assembly on a Cu(111) supported boron nitride monolayer | |
| Autori: | ||
| Data di pubblicazione: | 2015 | |
| Rivista: | ||
| Abstract: | We report the formation of a metal-organic network on a BN/Cu(111) template by codeposition of carbonitrile-functionalized porphyrin derivatives (2H-TPCN) with Co atoms in an ultrahigh vacuum environment. The resulting metallo-supramolecular structure explored by scanning tunneling microscopy and spectroscopy features a distinct 4-fold coordination motif. Furthermore, we demonstrate an in situ metalation of the tetrapyrrole macrocycles with deposited Co atoms yielding Co-TPCN directly on the BN sheet. Our results provide perspectives for the formation of coordination networks on BN and related systems featuring structural, electronic, and magnetic properties unachievable on metallic supports. | |
| Handle: | http://hdl.handle.net/11368/2869720 | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/ja511611r | |
| URL: | http://pubs.acs.org/journal/jacsat | |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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| File | Descrizione | Tipologia | Licenza | |
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| Controlling coordination reactions and assembly on a Cu(111) supported boron nitride monolayer.pdf | pdf articolo versione editoriale | Documento in Versione Editoriale | Digital Rights Management non definito | Administrator Richiedi una copia |
| Controlling coordination reactions - Supporting information.pdf | pdf Supporting information | Altro materiale allegato | Digital Rights Management non definito | Administrator Richiedi una copia |
