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EnglishA new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation.
| Titolo: | Zinc porphyrin-re(I) bipyridyl-fullerene triad: Synthesis, characterization, and kinetics of the stepwise electron-transfer processes initiated by visible excitation | |
| Autori: | ||
| Data di pubblicazione: | 2015 | |
| Rivista: | ||
| Abstract: | A new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation. | |
| Handle: | http://hdl.handle.net/11368/2887495 | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/ic502430e | |
| URL: | http://pubs.acs.org/journal/inocaj | |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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