A new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation.
Zinc porphyrin-re(I) bipyridyl-fullerene triad: Synthesis, characterization, and kinetics of the stepwise electron-transfer processes initiated by visible excitation / Cavigli, Paolo; DA ROS, Tatiana; Kahnt, Axel; Gamberoni, Marta; Indelli, Maria Teresa; Iengo, Elisabetta. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 54(2015):1(2015), pp. 280-292. [10.1021/ic502430e]
Zinc porphyrin-re(I) bipyridyl-fullerene triad: Synthesis, characterization, and kinetics of the stepwise electron-transfer processes initiated by visible excitation
DA ROS, TATIANA;IENGO, ELISABETTA
2015-01-01
Abstract
A new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation.| File | Dimensione | Formato | |
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