The reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts.

Shuttling as a Strategy to Control the Regiochemistry of Bis-Additions on Fullerene Derivatives

CARINI, MARCO;DA ROS, TATIANA;PRATO, MAURIZIO;
2016

Abstract

The reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts.
http://onlinelibrary.wiley.com/doi/10.1002/cphc.201501174/abstract
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11368/2888110
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