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EnglishThe reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts.
| Titolo: | Shuttling as a Strategy to Control the Regiochemistry of Bis-Additions on Fullerene Derivatives | |
| Autori: | ||
| Data di pubblicazione: | 2016 | |
| Rivista: | ||
| Abstract: | The reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts. | |
| Handle: | http://hdl.handle.net/11368/2888110 | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/cphc.201501174 | |
| URL: | http://onlinelibrary.wiley.com/doi/10.1002/cphc.201501174/abstract | |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| ChemPhysChem17(2016)1823 .pdf | Documento in Versione Editoriale | Digital Rights Management non definito | Administrator Richiedi una copia | |
| cphc201501174-sup-0001-misc_information.pdf | Supporting information | Altro materiale allegato | Digital Rights Management non definito | Administrator Richiedi una copia |
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