The reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts.
Shuttling as a Strategy to Control the Regiochemistry of Bis-Additions on Fullerene Derivatives
CARINI, MARCO;DA ROS, TATIANA;PRATO, MAURIZIO;
2016
Abstract
The reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts.File in questo prodotto:
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