The reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts.
Titolo: | Shuttling as a Strategy to Control the Regiochemistry of Bis-Additions on Fullerene Derivatives |
Autori: | |
Data di pubblicazione: | 2016 |
Rivista: | |
Abstract: | The reactivity of a fullerene-stoppered rotaxane, a C60 monoadduct, towards a second cycloaddition reaction is explored. The close proximity of the macrocycle to the fullerene sphere is able to allosterically influence the second cycloaddition reaction, giving rise to a selected mixture of bis-adducts. |
Handle: | http://hdl.handle.net/11368/2888110 |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/cphc.201501174 |
URL: | http://onlinelibrary.wiley.com/doi/10.1002/cphc.201501174/abstract |
Appare nelle tipologie: | 1.1 Articolo in Rivista |
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