Hazardous N-Containing System: Thermochemical and Computational Evaluation of the Intrinsic Molecular Reactivity of Some Aryl Azides and Diazides

The exothermic decompositions of the tosyl azide 1, five substituted aryl monoazides 2–6 and two diazides: 1-azido-4-(4-azidophenoxy)benzene 7 and 1-azido-4-[(4-azidophenyl)sulfanyl]benzene 8 were studied experimentally using DSC, weight loss TGA-FTIR and C80-FTIR techniques, and theoretically using the CHETAH software. Numerical modelling and electron impact mass spectrometry (EI-MS) were also performed to investigate the nature of the intrinsic molecular reactivity of azides 1–8, and the possible early stage rate-controlling of an oxidative self-heating process. Significant data were obtained in the instances of 4-methylbenzenesulfonyl azide 1, 4-azido-1,10-biphenyl-2,2-azido-1,10-biphenyl 3 and 1-azido-2-(trifluoromethyl)benzene 6. The most likely decomposition pathways of the azides are proposed to explain the observed thermal behavior.



Titolo: Hazardous N-Containing System: Thermochemical and Computational Evaluation of the Intrinsic Molecular Reactivity of Some Aryl Azides and Diazides
Autori: 
FRALEONI MORGERA, Alessandro
mostra contributor esterni 
Data di pubblicazione: 2008
Rivista: 
NEW JOURNAL OF CHEMISTRY  
Abstract: The exothermic decompositions of the tosyl azide 1, five substituted aryl monoazides 2–6 and two diazides: 1-azido-4-(4-azidophenoxy)benzene 7 and 1-azido-4-[(4-azidophenyl)sulfanyl]benzene 8 were studied experimentally using DSC, weight loss TGA-FTIR and C80-FTIR techniques, and theoretically using the CHETAH software. Numerical modelling and electron impact mass spectrometry (EI-MS) were also performed to investigate the nature of the intrinsic molecular reactivity of azides 1–8, and the possible early stage rate-controlling of an oxidative self-heating process. Significant data were obtained in the instances of 4-methylbenzenesulfonyl azide 1, 4-azido-1,10-biphenyl-2,2-azido-1,10-biphenyl 3 and 1-azido-2-(trifluoromethyl)benzene 6. The most likely decomposition pathways of the azides are proposed to explain the observed thermal behavior.
Handle: http://hdl.handle.net/11368/2888281
Digital Object Identifier (DOI): http://dx.doi.org/10.1039/b707931c
Appare nelle tipologie:1.1 Articolo in Rivista

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