We have studied the insertion of p-toluensulfonylmethyl isocyanide (TosMIC) on selected allenyl and propargyl complexes of palladium bearing diphenylphosphine quinoline as spectator ligand. The fast process gives different products depending on the tautomer involved in the reaction. Thus, the unsubstituted allenyl species yields the insertion complex with the isocyanide coordinated between the metal and the first allenyl carbon. On the other hand, the mixture of phenyl substituted allenyl and propargyl palladium complexes yields a novel species characterized by a cyclo-butenyl fragment directly coordinated to palladium. The solid state structure of such complex together with an exhaustive kinetic study of the whole process are reported.

The isocyanide insertion across the Pd-C bond of allenyl and propargyl palladium complexes bearing phosphoquinoline as spectator ligand. The synthesis of a palladium complex bearing a coordinated cyclobutenyl fragment

SCATTOLIN, THOMAS;
2017

Abstract

We have studied the insertion of p-toluensulfonylmethyl isocyanide (TosMIC) on selected allenyl and propargyl complexes of palladium bearing diphenylphosphine quinoline as spectator ligand. The fast process gives different products depending on the tautomer involved in the reaction. Thus, the unsubstituted allenyl species yields the insertion complex with the isocyanide coordinated between the metal and the first allenyl carbon. On the other hand, the mixture of phenyl substituted allenyl and propargyl palladium complexes yields a novel species characterized by a cyclo-butenyl fragment directly coordinated to palladium. The solid state structure of such complex together with an exhaustive kinetic study of the whole process are reported.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11368/2897089
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