Golden ring: A route for the direct AuCl3-catalyzed conversion of an enyne–amine into cyclopentadiene is reported. The mechanism for the catalysis is proposed and supported by a resting-state zwitterionic gold(III)-cyclopentadiene structure (see figure).
Isolation of a zwitterionic dienegold(III) Complex intermediate in the direct conversion of enyne-amines to cyclopentadienes / Melchionna, M., Nieger, M., Helaja, J.. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 16:28(2010), pp. 8262-8267. [10.1002/chem.201000988]
Isolation of a zwitterionic dienegold(III) Complex intermediate in the direct conversion of enyne-amines to cyclopentadienes
MELCHIONNA, MICHELE;
2010-01-01
Abstract
Golden ring: A route for the direct AuCl3-catalyzed conversion of an enyne–amine into cyclopentadiene is reported. The mechanism for the catalysis is proposed and supported by a resting-state zwitterionic gold(III)-cyclopentadiene structure (see figure).File in questo prodotto:
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