Golden ring: A route for the direct AuCl3-catalyzed conversion of an enyne–amine into cyclopentadiene is reported. The mechanism for the catalysis is proposed and supported by a resting-state zwitterionic gold(III)-cyclopentadiene structure (see figure).
Titolo: | Isolation of a zwitterionic dienegold(III) Complex intermediate in the direct conversion of enyne-amines to cyclopentadienes |
Autori: | |
Data di pubblicazione: | 2010 |
Rivista: | |
Abstract: | Golden ring: A route for the direct AuCl3-catalyzed conversion of an enyne–amine into cyclopentadiene is reported. The mechanism for the catalysis is proposed and supported by a resting-state zwitterionic gold(III)-cyclopentadiene structure (see figure). |
Handle: | http://hdl.handle.net/11368/2897568 |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/chem.201000988 |
URL: | http://www3.interscience.wiley.com/cgi-bin/fulltext/123567867/PDFSTART |
Appare nelle tipologie: | 1.1 Articolo in Rivista |
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