ArTS Archivio della ricerca di Trieste
ArTS è il sistema di gestione integrata dei dati della ricerca adottato dall' Università degli Studi di Trieste
EnglishAmine-richnitrogen-doped carbon nanodots(NCNDs) have been successfully used as co-reactant inelectrochemiluminescence (ECL) processes.Primary or ter-tiary amino groups on NCNDs have been studied as co-reactant sites for Ru(bpy)32+ECL, showing their eligibility aspowerful alternatives to tripropylamine (TPrA). We also reportthe synthesis and ECL behavior of anew covalently linkedhybrid of NCNDs and Ru(bpy)32+.Notably,the NCNDs in thehybrid act both as carrier for ECL labels and as co-reactant forECL generation. As aresult, the hybrid shows ahigher ECLemission as compared to the combination of the individualcomponents,suggesting the self-enhancing ECL of the ruthe-nium complex due to an intramolecular electron transferprocess.
| Titolo: | Amine-Rich Nitrogen-Doped Carbon Nanodots as a Platform for Self-Enhancing Electrochemiluminescence | |
| Autori: | ||
| Data di pubblicazione: | 2017 | |
| Stato di pubblicazione: | Pubblicato | |
| Rivista: | ||
| Abstract: | Amine-richnitrogen-doped carbon nanodots(NCNDs) have been successfully used as co-reactant inelectrochemiluminescence (ECL) processes.Primary or ter-tiary amino groups on NCNDs have been studied as co-reactant sites for Ru(bpy)32+ECL, showing their eligibility aspowerful alternatives to tripropylamine (TPrA). We also reportthe synthesis and ECL behavior of anew covalently linkedhybrid of NCNDs and Ru(bpy)32+.Notably,the NCNDs in thehybrid act both as carrier for ECL labels and as co-reactant forECL generation. As aresult, the hybrid shows ahigher ECLemission as compared to the combination of the individualcomponents,suggesting the self-enhancing ECL of the ruthe-nium complex due to an intramolecular electron transferprocess. | |
| Handle: | http://hdl.handle.net/11368/2902975 | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/anie.201611879 | |
| URL: | http://onlinelibrary.wiley.com/doi/10.1002/anie.201611879/abstract | |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| Carrara_et_al-2017-Angewandte_Chemie_International_Edition (1).pdf | Documento in Versione Editoriale | Digital Rights Management non definito | Administrator Richiedi una copia | |
| anie201611879-sup-0001-misc_information.pdf | Supporting information | Altro materiale allegato | Digital Rights Management non definito | Administrator Richiedi una copia |
| 3904_11368_2902975_EUT.pdf | Bozza finale post-referaggio (post-print) | Digital Rights Management non definito | Open Access Visualizza/Apri |
