Oxidation of primary and secondary alcohols, including two diols and glycerol, with H2O2 was catalyzed by the iron(II) complexes [FeL3](OTf)2 (L ¼ 2,20-bipyridine, 2,20-bipyrimidine, 1,10-phenanthroline and substituted derivatives) and [FeL2](OTf)2 (L ¼ bis(2-pyridinylmethyl)amine, 2,6-di(2-pyridyl)pyridine). The reactions were performed in acetonitrile, water or mixed solvent (typically water/acetonitrile 4:1) in a microwawe reactor at low power. Effect of addition of a cocatalyst, which in some cases improved the yields of the catalytic reaction, was investigated by means of NMR and UVeVisible techniques.
Microwave-assisted green oxidation of alcohols with hydrogen peroxide catalyzed by iron complexes with nitrogen ligands
Farnetti, Erica
2018-01-01
Abstract
Oxidation of primary and secondary alcohols, including two diols and glycerol, with H2O2 was catalyzed by the iron(II) complexes [FeL3](OTf)2 (L ¼ 2,20-bipyridine, 2,20-bipyrimidine, 1,10-phenanthroline and substituted derivatives) and [FeL2](OTf)2 (L ¼ bis(2-pyridinylmethyl)amine, 2,6-di(2-pyridyl)pyridine). The reactions were performed in acetonitrile, water or mixed solvent (typically water/acetonitrile 4:1) in a microwawe reactor at low power. Effect of addition of a cocatalyst, which in some cases improved the yields of the catalytic reaction, was investigated by means of NMR and UVeVisible techniques.File | Dimensione | Formato | |
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