Conformational distortions in bis-chelating nickelIJII) complexes with naphtholate Schiff base ligands bearing an alkyl chiral group at the imino nitrogen atoms are described. The single crystal X-ray analysis at 100 K by using synchrotron radiation of bisij1-((((R)- 1,2,2-trimethylpropyl)imino)methyl)-2-naphtholato]nickelIJII) shows an umbrella shape of sizeable bending. In addition, the unit cell of this complex contains 16 crystallographically independent units, a rare example of high Z′ value.

Conformation-directing chiral groups in bis(naphthaldiminato)nickel(ii) complexes: A rare example with 16 crystallographically independent units (: Z′)

Demitri, Nicola;Zangrando, Ennio
2018-01-01

Abstract

Conformational distortions in bis-chelating nickelIJII) complexes with naphtholate Schiff base ligands bearing an alkyl chiral group at the imino nitrogen atoms are described. The single crystal X-ray analysis at 100 K by using synchrotron radiation of bisij1-((((R)- 1,2,2-trimethylpropyl)imino)methyl)-2-naphtholato]nickelIJII) shows an umbrella shape of sizeable bending. In addition, the unit cell of this complex contains 16 crystallographically independent units, a rare example of high Z′ value.
File in questo prodotto:
File Dimensione Formato  
ganadu2018.pdf

Accesso chiuso

Tipologia: Documento in Versione Editoriale
Licenza: Copyright Editore
Dimensione 1.79 MB
Formato Adobe PDF
1.79 MB Adobe PDF   Visualizza/Apri   Richiedi una copia
c8ce01089g1.pdf

Accesso chiuso

Descrizione: Supporting information
Tipologia: Altro materiale allegato
Licenza: Copyright Editore
Dimensione 115.87 kB
Formato Adobe PDF
115.87 kB Adobe PDF   Visualizza/Apri   Richiedi una copia
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11368/2940098
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 3
  • ???jsp.display-item.citation.isi??? 3
social impact