One of the recent trends in electrocatalytic reactions involves the oxygen reduction reaction (ORR), where a new paradigm has been shaped to exploit this reaction for the synthesis of hydrogen peroxide (H2O2). H2O2 is a very versatile chemical of high commercial value, prepared currently through poorly sustainable processes. The emergence of metal-free carbon catalysts for the selective synthesis of H2O2 is expected to revolutionize ORR research, beckoning at the development of new industrial schemes. The complexities of the mechanism and the factors dominating the selectivity of the process have been unveiled through a combination of theoretical and experimental studies.

The Rise of Hydrogen Peroxide as the Main Product by Metal-Free Catalysis in Oxygen Reductions

Melchionna, Michele
Membro del Collaboration Group
;
Fornasiero, Paolo
Membro del Collaboration Group
;
Prato, Maurizio
Membro del Collaboration Group
2019-01-01

Abstract

One of the recent trends in electrocatalytic reactions involves the oxygen reduction reaction (ORR), where a new paradigm has been shaped to exploit this reaction for the synthesis of hydrogen peroxide (H2O2). H2O2 is a very versatile chemical of high commercial value, prepared currently through poorly sustainable processes. The emergence of metal-free carbon catalysts for the selective synthesis of H2O2 is expected to revolutionize ORR research, beckoning at the development of new industrial schemes. The complexities of the mechanism and the factors dominating the selectivity of the process have been unveiled through a combination of theoretical and experimental studies.
2019
Pubblicato
https://onlinelibrary.wiley.com/doi/full/10.1002/adma.201802920
File in questo prodotto:
File Dimensione Formato  
Melchionna_et_al-2019-Advanced_Materials.pdf

Accesso chiuso

Tipologia: Documento in Versione Editoriale
Licenza: Copyright Editore
Dimensione 1.16 MB
Formato Adobe PDF
1.16 MB Adobe PDF   Visualizza/Apri   Richiedi una copia
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11368/2940966
Citazioni
  • ???jsp.display-item.citation.pmc??? 9
  • Scopus 231
  • ???jsp.display-item.citation.isi??? 240
social impact