We describe a novel efficient photochemical procedure for the direct iodoperfluoroalkylation of terminal olefins. The process uses a simple and inexpensive perylenediimide (PDI) in an extremely low catalytic loading and occurs with visible light irradiation. The reported methodology is highly viable from a synthetic point of view, since it proceeds under mild reaction conditions with a significant rate of production. Preliminary mechanistic investigations are also reported.

Highly Performing Iodoperfluoroalkylation of Alkenes Triggered by the Photochemical Activity of Perylene Diimides

Rosso, Cristian
Membro del Collaboration Group
;
Filippini, Giacomo
Membro del Collaboration Group
;
Prato, Maurizio
Membro del Collaboration Group
2019-01-01

Abstract

We describe a novel efficient photochemical procedure for the direct iodoperfluoroalkylation of terminal olefins. The process uses a simple and inexpensive perylenediimide (PDI) in an extremely low catalytic loading and occurs with visible light irradiation. The reported methodology is highly viable from a synthetic point of view, since it proceeds under mild reaction conditions with a significant rate of production. Preliminary mechanistic investigations are also reported.
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https://onlinelibrary.wiley.com/doi/full/10.1002/cptc.201900018
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11368/2948206
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