C3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations.
Triphenylene based metal-pyridine cages / Berton, G.; Lorenzetto, T.; Borsato, G.; Sgarbossa, P.; Santo, C.; Visentin, F.; Fabris, F.; Scarso, A.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - ELETTRONICO. - 60:43(2019), pp. 151202."-"-151202."-". [10.1016/j.tetlet.2019.151202]
Triphenylene based metal-pyridine cages
Berton G.;Scarso A.
2019-01-01
Abstract
C3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations.| File | Dimensione | Formato | |
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