We investigate the clustering and phase separation of a model of ultrasoft, oppositely charged macroions by a combination of Monte Carlo and Molecular Dynamics simulations. Static and dynamic diagnostics, including the dielectric permittivity and the electric conductivity of the model, show that ion pairing induces a sharp conductor-insulator transition at low temperatures and densities, which impacts the separation into dilute and concentrated phases below a critical temperature. Preliminary evidence is presented for a possible tricritical nature of the phase diagram of the model.
Clustering, conductor-insulator transition and phase separation of an ultrasoft model of electrolytes / Coslovich, D; Hansen, Jp; Kahl, G. - In: SOFT MATTER. - ISSN 1744-683X. - 7:5(2011), pp. 1690-1693. [10.1039/c0sm01090a]
Clustering, conductor-insulator transition and phase separation of an ultrasoft model of electrolytes
Coslovich D;
2011-01-01
Abstract
We investigate the clustering and phase separation of a model of ultrasoft, oppositely charged macroions by a combination of Monte Carlo and Molecular Dynamics simulations. Static and dynamic diagnostics, including the dielectric permittivity and the electric conductivity of the model, show that ion pairing induces a sharp conductor-insulator transition at low temperatures and densities, which impacts the separation into dilute and concentrated phases below a critical temperature. Preliminary evidence is presented for a possible tricritical nature of the phase diagram of the model.Pubblicazioni consigliate
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