The Cover Feature shows a kaleidoscopic vision of the frontier empty orbitals of [60]fulleropyrrolidine embracing diverse [6,6] bonds, which poses a severe regioselectivity challenge for further ylide cycloaddition, resulting in a multitude of polyfunctionalization products. A combined kinetic and mechanistic study is reported to interrogate the thermodynamic drivers, leading to stable fulleropyrrolidine bis-adducts, using MW-assisted heating and ionic liquids additives.
Cover Feature: Microwave‐Assisted 1,3‐Dipolar Cycloaddition of Azomethine Ylides to [60]Fullerene: Thermodynamic Control of Bis‐Addition with Ionic Liquids Additives (Eur. J. Org. Chem. 25/2021)
Montellano, Alejandro;Carraro, Mauro;Prato, Maurizio
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2021-01-01
Abstract
The Cover Feature shows a kaleidoscopic vision of the frontier empty orbitals of [60]fulleropyrrolidine embracing diverse [6,6] bonds, which poses a severe regioselectivity challenge for further ylide cycloaddition, resulting in a multitude of polyfunctionalization products. A combined kinetic and mechanistic study is reported to interrogate the thermodynamic drivers, leading to stable fulleropyrrolidine bis-adducts, using MW-assisted heating and ionic liquids additives.File in questo prodotto:
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European J Organic Chem - 2021 - Martinis - Microwave‐Assisted 1 3‐Dipolar Cycloaddition of Azomethine Ylides to 60.pdf
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