The Cover Feature shows a kaleidoscopic vision of the frontier empty orbitals of [60]fulleropyrrolidine embracing diverse [6,6] bonds, which poses a severe regioselectivity challenge for further ylide cycloaddition, resulting in a multitude of polyfunctionalization products. A combined kinetic and mechanistic study is reported to interrogate the thermodynamic drivers, leading to stable fulleropyrrolidine bis-adducts, using MW-assisted heating and ionic liquids additives.

Cover Feature: Microwave‐Assisted 1,3‐Dipolar Cycloaddition of Azomethine Ylides to [60]Fullerene: Thermodynamic Control of Bis‐Addition with Ionic Liquids Additives (Eur. J. Org. Chem. 25/2021)

Montellano, Alejandro;Carraro, Mauro;Prato, Maurizio
;
2021

Abstract

The Cover Feature shows a kaleidoscopic vision of the frontier empty orbitals of [60]fulleropyrrolidine embracing diverse [6,6] bonds, which poses a severe regioselectivity challenge for further ylide cycloaddition, resulting in a multitude of polyfunctionalization products. A combined kinetic and mechanistic study is reported to interrogate the thermodynamic drivers, leading to stable fulleropyrrolidine bis-adducts, using MW-assisted heating and ionic liquids additives.
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https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.202100707
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11368/3026245
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