We present the synthesis of Sn(IV)-corrole complexes that bind to carboxylate moieties reversibly, via axial ligation. The systems have been predominantly characterized using H-1 NMR spectroscopy, X-ray crystallography, and MALDI mass spectrometry. The dynamic nature of the Sn(IV)-O2CR bond has been studied in solution using 2D-NMR spectroscopy.
Sn(IV)-corroles reversibly bind carboxylates in the axial position
Cavigli, P;Iengo, E
2023-01-01
Abstract
We present the synthesis of Sn(IV)-corrole complexes that bind to carboxylate moieties reversibly, via axial ligation. The systems have been predominantly characterized using H-1 NMR spectroscopy, X-ray crystallography, and MALDI mass spectrometry. The dynamic nature of the Sn(IV)-O2CR bond has been studied in solution using 2D-NMR spectroscopy.File in questo prodotto:
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