The interaction of H2 with a composite Pt/Ce 0.6Zr0.4O2/Al2O3 system and its redox properties are investigated by means of H2 and O 2 chemisorption, temperature programmed reduction (TPR) and desorption techniques. It is shown that the high H2 spillover capabilities of Pt/CeO2-ZrO2 are maintained even after supporting the system on Al2O3. The re-oxidation experiments performed on the reduced moieties show that the stability of Ce(III) species is increased by Al2O3, while the presence of Pt favours the re-oxidation.



Titolo: Interaction of molecular hydrogen with three-way catalyst model of Pt/Ce0.6Zr0.4O2/Al2O3 type
Autori: 
FORNASIERO, Paolo
MONTINI, TIZIANO
KASPAR, JAN
GRAZIANI, MAURO
mostra contributor esterni 
Data di pubblicazione: 2003
Rivista: 
JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL  
Abstract: The interaction of H2 with a composite Pt/Ce 0.6Zr0.4O2/Al2O3 system and its redox properties are investigated by means of H2 and O 2 chemisorption, temperature programmed reduction (TPR) and desorption techniques. It is shown that the high H2 spillover capabilities of Pt/CeO2-ZrO2 are maintained even after supporting the system on Al2O3. The re-oxidation experiments performed on the reduced moieties show that the stability of Ce(III) species is increased by Al2O3, while the presence of Pt favours the re-oxidation.
Handle: http://hdl.handle.net/11368/1694258
Digital Object Identifier (DOI): 10.1016/S1381-1169(03)00352-2
Appare nelle tipologie:1.1 Articolo in Rivista

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