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EnglishThe interaction of H2 with a composite Pt/Ce 0.6Zr0.4O2/Al2O3 system and its redox properties are investigated by means of H2 and O 2 chemisorption, temperature programmed reduction (TPR) and desorption techniques. It is shown that the high H2 spillover capabilities of Pt/CeO2-ZrO2 are maintained even after supporting the system on Al2O3. The re-oxidation experiments performed on the reduced moieties show that the stability of Ce(III) species is increased by Al2O3, while the presence of Pt favours the re-oxidation.
| Titolo: | Interaction of molecular hydrogen with three-way catalyst model of Pt/Ce0.6Zr0.4O2/Al2O3 type |
| Autori: | |
| Data di pubblicazione: | 2003 |
| Rivista: | |
| Abstract: | The interaction of H2 with a composite Pt/Ce 0.6Zr0.4O2/Al2O3 system and its redox properties are investigated by means of H2 and O 2 chemisorption, temperature programmed reduction (TPR) and desorption techniques. It is shown that the high H2 spillover capabilities of Pt/CeO2-ZrO2 are maintained even after supporting the system on Al2O3. The re-oxidation experiments performed on the reduced moieties show that the stability of Ce(III) species is increased by Al2O3, while the presence of Pt favours the re-oxidation. |
| Handle: | http://hdl.handle.net/11368/1694258 |
| Digital Object Identifier (DOI): | 10.1016/S1381-1169(03)00352-2 |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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