X-ray photoelectron spectra of the 3s core lines of NiO, CoO, FeO and MnO obtained on high-quality single crystals are interpreted on the basis of an impurity-cluster configuration-interaction model where the exchange and the intra-atomic M-shell charge redistribution energies are evaluated ab initio, Good agreement between the experimental and calculated binding energies and the intensity of the spectral components is obtained. These results clarify the interplay among the charge transfer, exchange and intra-atomic charge redistribution effects on the spectral structure.

A PROPER ANDERSON-HAMILTONIAN TREATMENT OF THE 3S PHOTOELECTRON-SPECTRA OF MnO, FeO, CoO AND NiO

PARMIGIANI, FULVIO
1996-01-01

Abstract

X-ray photoelectron spectra of the 3s core lines of NiO, CoO, FeO and MnO obtained on high-quality single crystals are interpreted on the basis of an impurity-cluster configuration-interaction model where the exchange and the intra-atomic M-shell charge redistribution energies are evaluated ab initio, Good agreement between the experimental and calculated binding energies and the intensity of the spectral components is obtained. These results clarify the interplay among the charge transfer, exchange and intra-atomic charge redistribution effects on the spectral structure.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11368/2558600
 Avviso

Registrazione in corso di verifica.
La registrazione di questo prodotto non è ancora stata validata in ArTS.

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact