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EnglishTwo diastereomeric forms of the μ4-oxo-bridged tetranuclear copper(II) complex [Cu4(O)(L)2(Ac)4] (where L=N2,O-donor Schiff-base ligand and Ac = acetate anion), differing for the bridging arrangement of the carboxylate groups, were individually synthesized and structurally characterized. Their formation was rationalized by DFT calculation and their catecholase-like activity was studied.
| Titolo: | Diastereomerism in tetranuclear copper(II) complexes of a phenol based “end-off” compartmental ligand | |
| Autori: | ||
| Data di pubblicazione: | 2012 | |
| Rivista: | ||
| Abstract: | Two diastereomeric forms of the μ4-oxo-bridged tetranuclear copper(II) complex [Cu4(O)(L)2(Ac)4] (where L=N2,O-donor Schiff-base ligand and Ac = acetate anion), differing for the bridging arrangement of the carboxylate groups, were individually synthesized and structurally characterized. Their formation was rationalized by DFT calculation and their catecholase-like activity was studied. | |
| Handle: | http://hdl.handle.net/11368/2829742 | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.inoche.2012.06.020 | |
| Appare nelle tipologie: | 1.1 Articolo in Rivista |
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