Styryl sulphones undergo nucleophilic addition, with the nucleophile adding at the α- or the β-position, with respect to the sulphone group; β-attack is normally favoured over α-attack. Factors which can change the regioselectivity in favour of the addition of the nucleophile to the α-position are discussed for heteronucleophiles as well as carbon nucleophiles.

Nucleophilic addition to styryl sulphones. Part I. A study on the regiochemistry

BENEDETTI, FABIO;FABRISSIN, SILVIO;RISALITI, AMERIGO
1983

Abstract

Styryl sulphones undergo nucleophilic addition, with the nucleophile adding at the α- or the β-position, with respect to the sulphone group; β-attack is normally favoured over α-attack. Factors which can change the regioselectivity in favour of the addition of the nucleophile to the α-position are discussed for heteronucleophiles as well as carbon nucleophiles.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11368/2843631
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