1-Substituted morpholino ethenes—III. Carbocyclic and Aliphatic Heterocyclic Compounds from 5-Membered Ring Derivatives

[4+2] Cycloaddition reaction of 1-(cyclopenten-1-y1)-1-morpholino ethene with β-nitrostyrene leads to tetrahydroindan and tetrahydroindanone derivatives. A [4+2] adduct of interest is also obtained in the reaction of the same substrate with mesyl chloride. Reactivity of the same electrophiles with the morpholino enamine of cyclopentyl-methyl ketone is also examined. Some stereochemical aspects of the above mentioned reactions are discussed.



Titolo: 1-Substituted morpholino ethenes—III. Carbocyclic and Aliphatic Heterocyclic Compounds from 5-Membered Ring Derivatives
Autori: 
BENEDETTI, FABIO
PITACCO, GIULIANA
VALENTIN, ENNIO
Data di pubblicazione: 1979
Rivista: 
TETRAHEDRON  
Abstract: [4+2] Cycloaddition reaction of 1-(cyclopenten-1-y1)-1-morpholino ethene with β-nitrostyrene leads to tetrahydroindan and tetrahydroindanone derivatives. A [4+2] adduct of interest is also obtained in the reaction of the same substrate with mesyl chloride. Reactivity of the same electrophiles with the morpholino enamine of cyclopentyl-methyl ketone is also examined. Some stereochemical aspects of the above mentioned reactions are discussed.
Handle: http://hdl.handle.net/11368/2853620
Digital Object Identifier (DOI): http://dx.doi.org/10.1016/0040-4020(79)80124-6
Appare nelle tipologie:1.1 Articolo in Rivista

File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
 
 
 
©2014 University of Trieste dove siamo Privacy
Piazzale Europa,1 34127 Trieste, Italia - Tel. +39 040.558.7111 - P.IVA 00211830328 - C.F. 80013890324 - P.E.C.: ateneo@pec.units.it
 Copyright © 2021