1-Substituted morpholino ethenes—III. Carbocyclic and Aliphatic Heterocyclic Compounds from 5-Membered Ring Derivatives

[4+2] Cycloaddition reaction of 1-(cyclopenten-1-y1)-1-morpholino ethene with β-nitrostyrene leads to tetrahydroindan and tetrahydroindanone derivatives. A [4+2] adduct of interest is also obtained in the reaction of the same substrate with mesyl chloride. Reactivity of the same electrophiles with the morpholino enamine of cyclopentyl-methyl ketone is also examined. Some stereochemical aspects of the above mentioned reactions are discussed.



Titolo: 1-Substituted morpholino ethenes—III. Carbocyclic and Aliphatic Heterocyclic Compounds from 5-Membered Ring Derivatives
Autori: 
BENEDETTI, FABIO
PITACCO, GIULIANA
VALENTIN, ENNIO
Data di pubblicazione: 1979
Rivista: 
TETRAHEDRON  
Abstract: [4+2] Cycloaddition reaction of 1-(cyclopenten-1-y1)-1-morpholino ethene with β-nitrostyrene leads to tetrahydroindan and tetrahydroindanone derivatives. A [4+2] adduct of interest is also obtained in the reaction of the same substrate with mesyl chloride. Reactivity of the same electrophiles with the morpholino enamine of cyclopentyl-methyl ketone is also examined. Some stereochemical aspects of the above mentioned reactions are discussed.
Handle: http://hdl.handle.net/11368/2853620
Digital Object Identifier (DOI): http://dx.doi.org/10.1016/0040-4020(79)80124-6
Appare nelle tipologie:1.1 Articolo in Rivista

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